203. "Alkali metal hydroxide–catalyzed C(sp)–H bond silylation" Anton Toutov,† Kerry Betz,† David Phillip Schuman, Wen-bo Liu, Alexey Fedorov, Brian M. Stoltz, and Robert H. Grubbs. J. Am. Chem. Soc. 2016, ASAP. [Supporting Information]. †Equal Contribution.

202. "Single-step synthesis of 3-hydroxycarbazoles by annulation of electron-rich anilines and quinones" Eugenia Pushkarskaya, Brian Wong, Chong Han, Simona Capomolla, Chunang Gu, Brian M. Stoltz, Haiming Zhang. Tetrahedron Lett. 201657, 5653. [Supporting Information].

201. "Iridium-Catalyzed Stereoselective Allylic Alkylation Reactions with Crotyl Chloride" J. Caleb Hethcox,† Samantha E. Shockley,† and Brian M. Stoltz. Angew. Chem. Int. Ed. 2016Early View. [Supporting Information]. †Equal Contribution.

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198. "Catalytic Anti-Markovnikov Transformations of Hindered Terminal Alkenes Enabled by Aldehyde-Selective Wacker-Type Oxidation" Kelly E. Kim, Jiaming Li, Robert H. Grubbs, and Brian M. Stoltz. J. Am. Chem. Soc. 2016ASAP. [Supporting Information]

196. "Enantioconvergent catalysis" Justin T. Mohr, Jared T. Moore, and Brian M. Stoltz. Beilstein J. Org. Chem. 201612, 2038.

195. "Potassium tert-Butoxide–Catalyzed Dehydrogenative Cross-Coupling of Heteroarenes with Hydrosilanes" Anton A. Toutov, Wen-Bo Liu, Brian M. Stoltz and Robert H. Grubbs. Org. Synth., 201693, 263.

194. "Iridium-Catalyzed Diastereo-, Enantio-, and Regioselective Allylic Alkylation with Prochiral Enolates" J. Caleb Hethcox,† Samantha E. Shockley,† and Brian M. Stoltz.ACS Catal., 20166, 6207. †Equal Contribution.

193. "Enantioselective, Convergent Synthesis of the Ineleganolide Core by a Tandem Annulation Cascade" Rob Craig, Jennifer L. Roizen, Russell Smith, Amanda C. Jones, Scott Virgil and Brian M. Stoltz. Chem. Sci, 2016Advance Article[Supporting Information]

192. "Escherichia coli K1 modulates peroxisome proliferator-activated receptor-gamma and glucose transporter-1 at the blood-brain barrier in neonatal meningitis"Subramanian Krishnan, Alexander C. Chang, Brian M. Stoltz, and Nemani V. Prasadarao. J. Infect. Dis., 2016214, 1092. This article was featured in a press release from Children's Hospital, Los Angeles

191. "Preparation of 1,5-Dioxaspiro[5.5]undecan-3-one" Robert A. Craig, II, Russell C. Smith, Beau P. Pritchett, Benzi I. Estipona, and Brian M. Stoltz. Org. Synth., 201693, 210.

190. "Ni-Catalyzed Enantioselective C-Acylation of α-Substituted Lactams" Masaki Hayashi, Shoshana Bachman, Satoshi Hashimoto, Chad C. Eichman, and Brian M. Stoltz.J. Am. Chem. Soc. 2016138, 8997. [Supporting Information]. Check out the Synfacts highlight.

189. "Synthesis of Aryl Ketoamides via Aryne Insertion into Imides" Austin C. Wright, Christopher K. Haley, Guillaume Lapointe, and Brian M. Stoltz. Org. Lett. 201618, 2793. [Supporting Information]

188. "Nickel-Catalyzed Intramolecular C−O Bond Formation: Synthesis of Cyclic Enol Ethers" Seo-Jung Han, Ryohei Doi, Brian M. Stoltz. Angew. Chem. Int. Ed. 201655, 7437. [Supporting Information]

186. "Enantioselective Synthesis of Caprolactam and Enone Precursors to the Heterocyclic DEFG Ring System of Zoanthenol" Jeffrey T. Bagdanoff, Douglas C. Behenna, Jennifer L. Stockdill, and Brian M. Stoltz. Eur. J. Org. Chem. 20162016, 2101. [Supporting Information]

185. "Enantioselective γ-Alkylation of α,β-Unsaturated Malonates and Ketoesters by a Sequential Ir-Catalyzed Asymmetric Allylic Alkylation/Cope Rearrangement" Wen-Bo Liu,† Noriko Okamoto,† Eric J. Alexy, Allen Y. Hong, Kristy Tran, and Brian M. Stoltz. J. Am. Chem. Soc. 2016138, 5234. †Equal Contribution. [Supporting Information]. Check out the Synfacts highlight!

184. "Catalytic enantioselective total synthesis of (+)-eucomic acid" Benzi I. Estipona,† Beau P. Pritchett, Robert A. Craig II, Brian M. Stoltz. Tetrahedron, 201672, 3707. †Caltech Undergrad. [Supporting Information]

183. "Synthetic Applications and Methodological Developments of Donor-Acceptor Cyclopropanes and Related Compounds" Nicholas R. O’Connor, John L. Wood, Brian M. Stoltz. Isr. J. Chem., 201656, 431.

182. "Development of a simple system for the oxidation of electron-rich diazo compounds to ketones" Nicholas R. O’Connor, Peter Bolgar, Brian M. Stoltz. Tetrahedron Lett., 201657, 849. [Supporting Information]

181. "Total Synthesis and Characterization of 7-Hypoquinuclidonium Tetrafluoroborate and 7-Hypoquinuclidone BF3 Complex" Marc Liniger, David G. VanderVelde, Michael K. Takase, Mona Shahgholi, Brian M. Stoltz. J. Am. Chem. Soc., 2016138, 969.  [Supporting Information]

 

Brian's Graduate and Postdoctoral Publications


18. "Welwitindolinone C synthetic studies. Construction of the welwitindolinone carbon skeleton via a transannular nitrone cycloaddition", David B. Freeman, Alexandra A. Holubec, Matthew W. Weiss, Julie A. Dixon, Akio Kakefuda, Masami Ohtsuka, Munenori Inoue, Rishi G. Vaswani, Hidenori Ohki, Brian D. Doan, Sarah E. Reisman, Brian M. Stoltz, Joshua J. Day, Ran N. Tao, Noah A. Dieterich, John L. Wood. Tetrahedron 2010Article In Press.

17. "Synthesis of C(3) Benzofuran-Derived Bisaryl Quaternary Centers: Approaches to Diazonamide A", Douglas E. Fuerst, Brian M. Stoltz, and John L. Wood. Org. Lett.20002, 3521. [Supporting Information]

16. "Enantioselective Total Synthesis of Nicandrenones", Brian M. Stoltz, Taichi Kano, and E. J. Corey. J. Am. Chem. Soc. 2000122, 9044. [Supporting Information]

15. "Mechanistic Insights into the Factors Determining Exo-Endo Selectivity in the Lewis Acid-Catalyzed Diels-Alder Reaction of 1,3-Dienes with 2-Cycloalkenones", Min Ge, Brian M. Stoltz, and E. J. Corey. Org. Lett. 20002, 1927.

14. "Cuprous Chloride Accelerated Stille Reactions. A General and Effective Coupling System for Sterically Congested Substrates and for Enantioselective Synthesis", Xiaojun Han, Brian M. Stoltz, and E. J. Corey. J. Am. Chem. Soc. 1999121, 7600. [Supporting Information]

13. "A Simple and Effective Procedure for Removal of Tri-n-butyltin Halides from Reaction Mixtures", Benjamin S. Edelson, Brian M. Stoltz and E. J. Corey. Tetrahedron Lett. 199940, 6729.

12. "Novel Annulation Products Derived by Selective Attack on the C(18) Angular Methyl Group of the Cardenolide Ouabain", E. J. Corey and Brian M. Stoltz. Tetrahedron Lett. 199940, 2061.

11. "Total Synthesis and Protein Kinase Activity of C(7) Methyl Derivatives of K252a", John L. Wood, Dejah T. Petsch, Brian M. Stoltz, Elizabeth M. Hawkins, Daniel Elbaum, and David R. Stover. Synthesis 1999Sup. 1, 1529.

10. "Application of Reactive Enols in Synthesis: A Versatile Efficient and Stereoselective Construction of the Welwitindolinone Carbon Skeleton", John L. Wood, Alexandra A. Holubec, Brian M. Stoltz, Matthew M. Weiss, Julie A. Dixon, Brian D. Doan, Mohammed F. Shamji, Jennifer M. Chen, and Timothy P. Heffron. J. Am. Chem. Soc. 1999121, 6326. [Supporting Information]

9. "Development of a Rhodium Carbenoid-Initiated Claisen Rearrangement for the Enantioselective Synthesis of α-Hydroxy Carbonyl Compounds", John L. Wood, George A. Moniz, Derek A. Pflum, Brian M. Stoltz, Alexandra A. Holubec, and Hans-Jürgen Dietrich. J. Am. Chem. Soc. 1999121, 1748. [Supporting Information]

8. "The Design and Implementation of an Efficient Synthetic Approach to Pyranosylated Indolocarbazoles: The Total Synthesis of (+)-RK286c, (+)-MLR-52, (+)-Staurosporine, and (-)-TAN-1030a", John L. Wood, Brian M. Stoltz, Steven N. Goodman, and Kenolisa Onwueme. J. Am. Chem. Soc. 1997119, 9652. [Supporting Information]

7. "The Design and Implementation of an Efficient Synthetic Approach to Furanosylated Indolocarbazoles: The Total Synthesis of (+)- and (-)-K252a", John L. Wood, Brian M. Stoltz, Hans-Jürgen Dietrich, Derek A. Pflum, and Dejah T. Petsch. J. Am. Chem. Soc. 1997119, 9641. [Supporting Information]

6. "The Total Synthesis of Indolocarbazole Natural Products K252c, (+)-K252a, (+)-RK-286c, (+)-MLR-52, (-)-TAN-1030a, and (+)-Staurosporine", Brian M. Stoltz, Ph.D. Thesis, Yale UniversityMay 1997.

5. "The Total Synthesis of (+)-RK-286c, (+)-MLR-52, (+)-Staurosporine and (+)-K252a", John L. Wood, Brian M. Stoltz, and Steven N. Goodman. J. Am. Chem. Soc.1996118, 10656. [Supporting Information]. (This paper was featured in a C&EN. News of the Week article.)

4. "The Synthesis of Desamido Analogs of Staurosporine, RK-286c, and TAN-1030a. A Model for the Synthesis of Both Furanosylated and Pyranosylated Indolocarbazole Natural Products", John L. Wood, Brian M. Stoltz, Kenolisa Onwueme and Steven N. Goodman. Tetrahedron Lett. 199637, 7335.

3. "The Stereoselective Ring Contraction of a Pyranosylated Indolocarbazole. A Biosynthetic Link Between K252a and Staurosporine?", Brian M. Stoltz and John L. Wood. Tetrahedron Lett. 199637, 3929.

2. "A Ring Expansion Approach to Pyranosylated Indolocarbazoles", Brian M. Stoltz and John L. Wood. Tetrahedron Lett. 199536, 8543.

1. "The Total Synthesis of (+)- and (-)-K252a", John L. Wood, Brian M. Stoltz, and Hans-Jürgen Dietrich. J. Am. Chem. Soc. 1995117, 10413.

Patents


"Palladium-catalyzed decarbonylation of fatty acid anhydrides for the production of linear alpha olefins", Yiyang Liu, Brian M. Stoltz, Robert H. Grubbs, Alexey Fedorov, and Kelly E. Kim United States Patent US 9440891, 2016.

"Synthetic Transtaganolide and Basiliolide Products, and Synthesis Methods Thereof", Hosea Nelson, Kei Murakami, Scott C. Virgil, Brian M. Stoltz, Jonathan R. Gordon.United States Patent US 9422259, 2016.

"Method of preparing Z-alkene-containing insect pheromones", Eric A. Bercot and Brian M. Stoltz. United States Patent US 9181164, 2015.

"Inhibitors of P97", Steven J. Brown, Tsui-Fen Chou, Raymond Deshaies, Amanda C. Jones, Hugh Rosen, Brian M. Stoltz. United States Patent US 9089572, 2015.

"Synthetic Transtaganolide and Basiliolide Products, and Synthesis Methods Thereof", Hosea Nelson, Kei Murakami, Scott C. Virgil, Brian M. Stoltz, Jonathan R. Gordon.United States Patent US 8912347, 2014.

"Quaternary Heteroatom Containing Compounds,", Brian M. Stoltz, Scott C. Virgil, David E. White, Taiga Yurino, Yiyang Liu, Douglas C. Behenna, Douglas Duquette, and Christian Eidamshaus. United States Patent US 8822679, 2014.

"Liphagal Enantiomers and their Derivatives and Precursors, and Enantioselective Methods of Making the Same,", Brian M. Stoltz, Ryan McFadden, Scott C. Virgil, Helene Kolding, Jennifer L. Alleva, and Joshua J. Day United States Patent US 8653307, 2014.

"Certain Chemical Entities, Compositions, and Methods", Zhe Yang, Scott Collibee, Alex R. Muci, Jianchao Wang, Luke W. Ashcraft, Jeff Gardina, Brian M. Stoltz, Gustave Bergnes, and Bradley P. Morgan. United States Patent US 7989469, 2011.

"Enantioselective, Catalytic Allylation of Ketones and Olefins", Douglas C. Behenna, Brian M. Stoltz, Justin T. Mohr, Andrew M. Harned. United States Patent US 7235698,2007.

"Methods and Compositions for Enantioselective Oxidation Reactions", Eric M. Ferreira, Brian M. Stoltz. United States Patent US 7166754, 2007.

"Chemical Reagents Capable of Selective Attachment to and Reaction with Peptides and Proteins", Jesse L. Beauchamp, Ryan R. Julian, Brian M. Stoltz and Jeremy A. May.United States Patent Application US 2005/0010059, 2005.

"Glycosylated Indolocarbazole Synthesis", John L. Wood, Brian M. Stoltz, Hans-Jürgen Dietrich, and Derek A. Pflum. Worldwide Patent WO 9707081, 1997. Also United States Patent US 7038043 and United States Patent US 6037468.