180. "Catalytic C–H bond silylation of aromatic heterocycles" Anton A Toutov,† Wen-Bo Liu,† Kerry N. Betz, Brian M. Stoltz. Robert H. Grubbs. Nat. Protoc., 201510, 1897. †Equal Contribution.

179. "Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Cyclopentanones" Robert A. Craig II,† Steven A. Loskot,† Justin T. Mohr, Douglas C. Behenna, Andrew M. Harned, Brian M. Stoltz. Org. Lett., 201517, 5160. †Equal Contribution. [Supporting Information]. This article was featured in Synfacts!

178. "Label-free detection of single nanoparticles and biological molecules using microtoroid optical resonators" Judith Su, Alexander F.G. Goldberg, Brian M. Stoltz. Light Sci. Appl., 20165, e16001.

177. "Preparation of (S)-tert-ButylPyOx and Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids" Jeffrey C. Holder, Samantha E. Shockley, Mario P. Wiesenfeldt, Hideki Shimizu, Brian M. Stoltz. Org. Synth., 201592, 247.

176. "Palladium(II)-Catalyzed Allylic C-H Oxidation of Hindered Substrates Featuring Tunable Selectivity Over Extent of Oxidation" Xiangyou Xing,† Nicholas R. O'Connor,†Brian M. Stoltz. Angew. Chem. Int. Ed., 201554, 11186. †Equal Contribution. [Supporting Information]

174. "Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to α,β-Unsaturated Cyclic Electrophiles" Samantha E. Shockley, Jeffrey C. Holder, Brian M. Stoltz. Org. Process Res. Dev., 201519, 974.

173. "An Efficient Protocol for the Palladium-Catalyzed Asymmetric Decarboxylative Allylic Alkylation Using Low Palladium Concentrations and a Palladium(II) Precatalyst" Alexander N. Marziale, Douglas C. Duquette, Robert A. Craig II, Kelly E. Kim, Marc Liniger, Yoshitaka Numajiri, Brian M. Stoltz. Adv. Synth. Catal. 2015357, 2238.[Supporting Information]

171. "Construction of Tertiary Chiral Centers by Pd-catalyzed Asymmetric Allylic Alkylation of Prochiral Enolate Equivalents" Yusuke Kita, Yoshitaka Numajiri, Noriko Okamoto, Brian M. Stoltz. Tetrahedron 201571, 6349. [Supporting Information]

170 "Exceedingly Efficient Synthesis of (±)-Grandifloracin and Acylated Analogues" Magnus Bergner, Douglas C. Duquette, Linda Chio, Brian M. Stoltz. Org. Lett. 201517, 3008. [Supporting Information]

169. "Enantioselective Synthesis of Dialkylated N-Heterocycles by Palladium-Catalyzed Allylic Alkylation" Yoshitaka Numajiri, Gonzalo Jiménez-Osés, Bo Wang, Ken N. Houk, Brian M. Stoltz. Org. Lett. 201517, 1082. [Supporting Information]

168. "Catalytic Enantioselective Construction of Quaternary Stereocenters: Assembly of Key Building Blocks for the Synthesis of Biologically Active Molecules" Yiyang Liu, Seo-Jung Han, Wen-Bo Liu, and Brian M. Stoltz. Acc. Chem. Res. 201548, 740. Please also see Prof. Paul Wender's accompanying editorial, entitled "Art, Architecture, and the Molecular Frontier."

167. "Silylation of C–H bonds in Aromatic Heterocycles by an Earth-abundant Metal Catalyst" Anton A. Toutov,† Wen-Bo Liu,† Kerry N. Betz, Alexey Fedorov, Brian M. Stoltz, Robert H. Grubbs. Nature 2015518, 80. †Equal Contribution. [Supporting Information]. This article was featured in Synfacts!

166. "Selective Syntheses of Leuconolam, Leuconoxine, and Mersicarpine Alkaloids from a Common Intermediate through Regiocontrolled Cyclizations by Staudinger Reactions" Zining Li, Qian Geng, Zhe Lv, Beau P. Pritchett, Katsuaki Baba, Yoshitaka Numajiri, Brian M. Stoltz, Guangxin Liang. Org. Chem. Front. 20152, 236.[Supporting Information]

165. "Enantioselective Synthesis of α-Quaternary Mannich Adducts by Palladium-Catalyzed Allylic Alkylation: Total Synthesis of (+)-Sibirinine" Yoshitaka Numajiri, Beau P. Pritchett, Koji Chiyoda, Brian M. Stoltz. J. Am. Chem. Soc. 2015137, 1040. [Supporting Information] This article was featured in Synfacts!

164. "Mechanistic Analysis of an Asymmetric Palladium-Catalyzed Conjugate Addition of Arylboronic Acids to β-Substituted Cyclic Enones" Cornelia L. Boeser, Jeffrey C. Holder, Buck L. H. Taylor, K. N. Houk, Brian M. Stoltz, Richard N. Zare. Chem. Sci. 20156, 1917. [Supporting Information]

163. "Synthesis of Diverse β-Quaternary Ketones via Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Cyclic Enones" Jeffrey C. Holder, Emmett D. Goodman, Kotaro Kikushima, Michele Gatti, Alexander N. Marziale, Brian M. Stoltz. Tetrahedron 201571, 5781.

162. "Evolution of a Unified, Stereodivergent Approach to the Synthesis of Communesin F and Perophoramidine" Seo-Jung Han, Florian Vogt, Jeremy A. May, Shyam Krishnan, Michele Gatti, Scott C. Virgil, Brian M. Stoltz. J. Org Chem. 201580, 528. [Supporting Information]

161. "Enantioselective Synthesis of α-Secondary and α-Tertiary Piperazin-2-ones and Piperazines by Catalytic Asymmetric Allylic Alkylation" Katerina M. Korch, Christian Eidamshaus, Douglas C. Behenna, Sangkil Nam, David Horne, Brian M. Stoltz. Angew. Chem. Int. Ed. 201554, 179. Also in press here. [Supporting Information]

160. "A Catalytic, Enantioselective Formal Synthesis of (+)-Dichroanone and (+)-Taiwaniaquinone H" Samantha E. Shockley, Jeffrey C. Holder, Brian M. Stoltz. Org. Lett.201416, 6362. [Supporting Information]

158. "Formal total syntheses of classic natural product target molecules via palladium-catalyzed enantioselective alkylation" Yiyang Liu, Marc Liniger, Ryan M. McFadden, Jenny L. Roizen, Jacquie Malette, Corey M. Reeves, Douglas C. Behenna, Masaki Seto, Jimin Kim, Justin T. Mohr, Scott C. Virgil and Brian M. Stoltz. Beilstein J. Org. Chem. 201410, 2501. [Supporting Information]

157. "The Total Syntheses of Basiliolide C, epi-Basiliolide C, and Protecting-Group-Free Total Syntheses of Transtaganolides C and D" Jonny R. Gordon, Hosea M. Nelson, Scott C. Virgil, Brian M. Stoltz. J. Org. Chem. 201479. 9740. [Supporting Information]

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156. "A New Method for the Cleavage of Nitrobenzyl Amides and Ethers" Seo-Jung Han, Gabriel Fernando de Melo, Brian M. Stoltz. Tet. Lett. 201455, 6467.

155. "Highly functionalized donor–acceptor cyclopropanes applied toward the synthesis of the Melodinus alkaloids" Alexander F.G. Goldberg, Robert A. Craig II,† Nicholas R. O’Connor,† Brian M. Stoltz. Tet. Lett. 201456, 2983. †Equal Contribution

154. "A Diastereodivergent Synthetic Strategy for the Syntheses of Communesin F and Perophoramidine" Seo-Jung Han, Florian Vogt, Shyam Krishnan, Jeremy A. May, Michele Gatti, Scott C. Virgil, Brian M. Stoltz. Org. Lett. 201416, 3316. [Supporting Information]

153. "Biosynthesis and Chemical Synthesis of Presilphiperfolanol Natural Products" Allen Y. Hong, Prof. Brian M. Stoltz. Angew. Chem. Int. Ed. 201453, 5248. Also in press here.

151. "Palladium-catalyzed decarboxylative allylic alkylation of diastereomeric β-ketoesters" Sandy Ma, Corey M. Reeves, Robert A. Craig II, Prof. Brian M. Stoltz.Tetrahedron 201470, 4208. [Supporting Information]

150. "Stereoselective Lewis Acid Mediated (3+2) Cycloadditions of N-H- and N-Sulfonylaziridines with Heterocumulenes" Robert A. Craig II, Nicholas R. O'Connor, Dr. Alexander F. G. Goldberg, Prof. Brian M. Stoltz. Chem. — Eur. J. 201420. 4806. [Supporting Information]

149. "Toward a Symphony of Reactivity: Cascades Involving Catalysis and Sigmatropic Rearrangements" Amanda Jones, Brian M. Stoltz*, Jeremy A. May, Richmond Sarpong. Angew. Chem. Int. Ed. 201453, 2556. Also in press at  Angew. Chem. 2014 126, 2590.

148. "Gas Phase Production and Loss of Isoprene Epoxydiols" Kelvin H. Bates, John D. Crounse, Jason M. St. Clair, Nathan B. Bennett, Tran B. Nguyen, John H. Seinfeld, Brian M. Stoltz, and Paul O. Wennberg. J. Phys. Chem. A 2014118, 1237. [Supporting Information]

147. "Palladium-Catalyzed Decarbonylative Dehydration of Fatty Acids for the Production of Linear Alpha Olefins" Yiyang Liu, Kelly E. Kim, Myles B. Herbert, Alexey Fedorov, Robert H. Grubbs, Brian M. Stoltz. Adv. Synth. Catal. 2014356, 130. [Supporting Information]. Additionally, this article was featured on the organic-chemistry.org webportal, which can be accessed here.

145. "Enantio-, Diastereo- and Regioselective Iridium-Catalyzed Asymmetric Allylic Alkylation of Acyclic β-Ketoesters" Wen-Bo Liu, Corey M. Reeves, and Brian M. Stoltz.J. Am. Chem. Soc. 2013135, 17298. [Supporting Information]This article was Synfact of the Month!

144. "Asymmetric Synthesis of QUINAP via Dynamic Kinetic Resolution" Vikram Bhat, Su Wang, Brian M. Stoltz, and Scott C Virgil. J. Am. Chem. Soc. 2013135, 16829.[Supporting Information]This article was featured in Synfacts!

143. "Angiotensin receptor I - A novel target for preventing neonatal meningitis in mice by Escherichia coli K1" Subramanian Krishnan, Muthusamy V. Shanmuganathan, Douglas Behenna, Brian M. Stoltz and Nemani V. Prasadarao. J. Infect. Dis. 2013209, 409. [Supporting Information]

142. "Mechanism and Enantioselectivity in Palladium-Catalyzed Conjugate Addition of Arylboronic Acids to β-Substituted Cyclic Enones: Insights from Computation and Experiment" Jeffrey C. Holder, Lufeng Zou, Alexander N. Marziale, Peng Liu, Yu Lan, Michele Gatti, Kotaro Kikushima, K. N. Houk, and Brian M. Stoltz. J. Am. Chem. Soc. 2013135, 14996. [Supporting Information]

141. "A scalable synthesis of the (S)-4-(tert-butyl)-2-(pyridin-2-yl)-4,5-dihydrooxazole ((S)-t-BuPyOx) ligand" Hideki Shimizu, Jeffrey C. Holder and Brian M. Stoltz.Beilstein J. Org. Chem. 20139, 1637. [Supporting Information]

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139. "Enantioselective Synthesis of the 5–6–7 Carbocyclic Core of the Gagunin Diterpenoids" Grant M. Shibuya , John A. Enquist , Jr., and Brian M. Stoltz. Org. Lett. 201315, 3480. [Supporting Information]

138. "Selective Nucleic Acid Capture with Shielded Covalent Probes" Jeffrey R. Vieregg, Hosea M. Nelson, Brian M. Stoltz, and Niles A. Pierce. J. Am. Chem. Soc. 2013135, 9691. [Supporting Information]

137. "Enantioselective Construction of α-Quaternary Cyclobutanones by Catalytic Asymmetric Allylic Alkylation" Corey M. Reeves, Christian Eidamshaus, Jimin Kim, and Brian M. Stoltz. Angew. Chem. Int. Ed. 201352, 6718. [Supporting Information] This article was featured in Synfacts!

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136. "Total Syntheses of (−)-Transtaganolide A, (+)-Transtaganolide B, (+)-Transtaganolide C, and (−)-Transtaganolide D and Biosynthetic Implications" Hosea M. Nelson, Jonny R. Gordon, Scott C. Virgil, and Brian M. Stoltz. Angew. Chem. Int. Ed. 201352, 6699. [Supporting Information]

134. "Development of a palladium-catalyzed decarboxylative cross-coupling of (2-azaaryl)carboxylates with aryl halides" Christopher K. Haley, Christopher D. Gilmore, and Brian M. Stoltz. Tetrahedron. 201369, 5732.

133. "Expanding Insight into Asymmetric Palladium-Catalyzed Allylic Alkylation of N-Heterocyclic Molecules and Cyclic Ketones" Nathan B. Bennett,† Douglas C. Duquette,† Jimin Kim, Wen-Bo Liu, Alexander N. Marziale, Douglas C. Behenna, Scott C. Virgil, and Brian M. Stoltz. Chem. — Eur. J. 201319, 4414. [Supporting Information]. †Equal Contribution

132. "Use of a palladium(II)-catalyzed oxidative kinetic resolution in synthetic efforts toward bielschowskysin" Michael E. Meyer, John H. Phillips, Eric M. Ferreira, and Brian M. Stoltz. Tetrahedron 201369, 7627.

131. "Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Heterocyclic Acceptors" Jeffrey C. Holder,† Alexander N. Marziale,† Michele Gatti, Bin Mao, and Brian M. Stoltz. Chem. — Eur. J. 201219, 74. [Supporting Information]. †Equal Contribution

130. "Rapid and Convergent Synthesis of a 2,4’-Linked Tri-oxazole in an Approach to Poly-oxazoles" Daniel D. Caspi, Haiming Zhang, Scott C. Virgil, Fabian M. Piller, and Brian M. Stoltz. Heterocycles. 201286, 1003. [Supporting Information].

129. "The Reaction Mechanism of the Enantioselective Tsuji Allylation: Inner-Sphere and Outer-Sphere Pathways, Internal Rearrangements, and Asymmetric C–C Bond Formation" John A. Keith, Douglas C. Behenna, Nathaniel Sherden, Justin T. Mohr, Sandy Ma, Smaranda C. Marinescu, Robert J. Nielsen, Jonas Oxgaard, Brian M. Stoltz and William A. Goddard, III. J. Am. Chem. Soc. 2012134, 19050. [Supporting Information].

128. "Enantioselective Synthesis of a Hydroxymethyl-cis-1,3-cyclopentenediol Building Block" Robert A. Craig, II, Jennifer L. Roizen, Russell C. Smith, Amanda C. Jones, and Brian M. Stoltz. Org. Lett. 201214, 5716. [Supporting Information].

127. "Lewis Acid Mediated (3 + 2) Cycloadditions of Donor–Acceptor Cyclopropanes with Heterocumulenes" Alexander F. G. Goldberg, Nicholas R. O'Connor,† Robert A. Craig, II† and Brian M. Stoltz. Org. Lett. 201214, 5314. [Supporting Information]. †Equal Contribution

125. "A C–N Insertion of β-Lactam to Benzyne: Unusual Formation of Acridone" Jimin Kim and Brian M. Stoltz. Tetrahedron Lett. 201253, 4994.

124. "A Comprehensive History of Arynes in Natural Product Total Synthesis" Pamela M. Tadross and Brian M. Stoltz. Chem. Rev. 2012112, 3550.

123. "Enantioselective construction of quaternary N-heterocycles by palladium-catalysed decarboxylative allylic alkylation of lactams" Douglas C. Behenna, Yiyang Liu, Taiga Yurino, Jimin Kim, David E. White, Scott C. Virgil and Brian M. Stoltz. Nature Chem. 20124, 130. [Supporting Information]. This article was featured in a press release entitled "Caltech Chemists Devise Chemical Reaction that Holds Promise for New Drug Development".

122. "Palladium-catalyzed asymmetric alkylation in the synthesis of cyclopentanoid and cycloheptanoid core structures bearing all-carbon quaternary stereocenters" Allen Y. Hong, Nathan B. Bennett, Michael R. Krout, Thomas Jensen, Andrew M. Harned, Brian M. Stoltz. Tetrahedron 201167, 10234. [Supporting Information].

121. "Enantioselective Decarboxylative Alkylation Reactions: Catalyst Development, Substrate Scope, and Mechanistic Studies" Douglas C. Behenna, Justin T. Mohr, Nathaniel H. Sherden, Smaranda C. Marinescu, Andrew M. Harned, Kousuke Tani, Masaki Seto, Sandy Ma, Zoltán Novák, Michael R. Krout, Ryan M. McFadden, Jennifer L. Roizen, John A. Enquist Jr., David E. White, Samantha R. Levine, Krastina V. Petrova, Akihiko Iwashita, Scott C. Virgil, Brian M. Stoltz. Chem. — Eur. J. 201117, 14199. [Supporting Information].

120. "Synthesis of enantioenriched γ-quaternary cycloheptenones using a combined allylic alkylation/Stork–Danheiser approach: preparation of mono-, bi-, and tricyclic systems" Nathan B. Bennett, Allen Y. Hong, Andrew M. Harned and Brian M. Stoltz. Org. Biomol. Chem. 201210, 56. [Supporting Information]. (This article was one of the top ten downloaded articles for the month of October).

119. "A Palladium-Catalyzed Vinylcyclopropane (3 + 2) Cycloaddition Approach to the Melodinus Alkaloids" Alexander F. G. Goldberg and Brian M. Stoltz. Org. Lett. 201113, 4474. (This article was among the top 20 accessed articles for the month of July). [Supporting Information].

118. "Total Syntheses of Cyanthiwigins B, F, and G" John A. Enquist Jr., Scott C. Virgil and Brian M. Stoltz. Chem. – Eur. J. 201117, 9957. [Supporting Information].

117. "A rapid and convergent synthesis of the integrastatin core" Pamela M. Tadross, Pradeep Bugga and Brian M. Stoltz. Org. Biomol. Chem. 20119, 5354. [Supporting Information]. (This article was selected as an OBC HOT article, and was among the top 10 accessed articles of the month).

116. "The Catalytic Enantioselective Total Synthesis of (+)-Liphagal" Joshua J. Day, Ryan M. McFadden, Scott C. Virgil, Helene Kolding, Jennifer L. Alleva, and Brian M. Stoltz. Angew. Chem., Int. Ed. 201150, 6814. [Supporting Information]. This article was featured as a SYNFACT of the month!

115. "Palladium-Catalyzed, asymmetric Baeyer–Villiger oxidation of prochiral cyclobutanones with PHOX ligands" Kimberly S. Petersen and Brian M. Stoltz. Tetrahedron201167, 4352-4357. (This article was highlighted in Org. Process Res. Dev. as an item of interest!)

113. "Benzannulated Bicycles by Three-Component Aryne Reactions" Kevin M. Allan, Christopher D. Gilmore, and Brian M. Stoltz. Angew. Chem., Int. Ed. 201150, 4488. [Supporting Information]. This article was featured in an Angew. Chem. Highlight article!

112. "A General Approach to the Basiliolide/Transtaganolide Natural Products: Total Syntheses of Basiliolide B, epi-8-Basiliolide B, Transtaganolide C, and Transtaganolide D" Hosea M. Nelson, Kei Murakami, Scott C. Virgil, and Brian M. Stoltz. Angew. Chem., Int. Ed. 201150, 3688. [Supporting Information]. This article was featured in Synfacts!

111. "Reversible inhibitor of p97, DBeQ, impairs both ubiquitin-dependent and autophagic protein clearance pathways" Tsui-Fen Chou, Steve J. Brown, Dmitriy Minond, Brian E. Nordin, Kelin Li, Amanda C. Jones, Peter Chase, Patrick R. Porubsky, Brian M. Stoltz, Frank J. Schoenen, Matthew P. Patricelli, Peter Hodder, Hugh Rosen, and Raymond J. Deshaies. P. Natl. Acad. Sci. USA 2011108, 4834. [Supporting Information]

110. "Ring-Contraction Strategy for the Practical, Scalable, Catalytic Asymmetric Synthesis of Versatile γ-Quaternary Acylcyclopentenes" Allen Y. Hong, Michael R. Krout, Thomas Jensen, Nathan B. Bennett, Andrew M. Harned, and Brian M. Stoltz. Angew. Chem., Int. Ed. 201150, 2756. [Supporting Information]

109. "A Catalytic, Asymmetric Formal Synthesis of (+)-Hamigeran B" Herschel Mukherjee, Nolan T. McDougal, Scott C. Virgil, and Brian M. Stoltz. Org Lett. 201113, 825. [Supporting Information]

108. "Confirmation of the absolute configuration of (–)-aurantioclavine" Douglas C. Behenna, Shyam Krishnan, and Brian M. Stoltz. Tetrahedron Lett. 201052, 2152.[Supporting Information]

107. "Rapid synthesis of an electron-deficient t-BuPHOX ligand: cross-coupling of aryl bromides with secondary phosphine oxides" Nolan T. McDougal, Jan Streuff, Herschel Mukherjee, Scott C. Virgil and Brian M. Stoltz. Tetrahedron Lett. 201051, 5550.

106. "High-Throughput Screening of the Asymmetric Decarboxylative Alkylation Reaction of Enolate-Stabilized Enol Carbonates" Nolan T. McDougal, Scott C. Virgil and Brian M. Stoltz. Synlett 2010, 1712.

105. "A general enantioselective route to the chamigrene natural product family" David E. White, Ian C. Stewart, Brinton A. Seashore-Ludlow, Robert H. Grubbs and Brian M. Stoltz. Tetrahedron 201066, 4668. [Supporting Information]

104. "Efforts toward rapid construction of the cortistatin A carbocyclic core via enyne-ene metathesis" Corinne Baumgartner, Sandy Ma, Qi Liu and Brian M. Stoltz. Org. Biomol. Chem. 20108, 2915. [Supporting Information]

103. "NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist", Gregory R. Fulmer, Alexander J. M. Miller, Nathaniel H. Sherden, Hugo E. Gottlieb, Abraham Nudelman, Brian M. Stoltz, John E. Bercaw, and Karen I. Goldberg. Organometallics 201029, 2176. [Supporting Information]

101. "Regioselective Reactions of Highly Substituted Arynes", Pamela M. Tadross, Christopher D. Gilmore, Pradeep Bugga, Scott C. Virgil, and Brian M. Stoltz. Org. Lett.201012, 1224. [Supporting Information]

100. "A Palladium-catalysed enolate alkylation cascade for the formation of adjacent quaternary and tertiary stereocentres", Jan Streuff, David E. White, Scott C. Virgil, and Brian M. Stoltz. Nature Chem. 20102, 192. [Supporting Information]. (This article was also featured in Chem. Eng. News 201088, 30-31 and Synfacts 20106, 685)

99. "The Palladium-Catalyzed Aerobic Kinetic Resolution of Secondary Alcohols: Reaction Development, Scope, and Applications", David C. Ebner, Jeffrey T. Bagdanoff, Eric M. Ferreira, Ryan M. McFadden, Daniel D. Caspi, Raissa M. Trend, and Brian M. Stoltz. Chem - Eur J 200915, 12978. [Supporting Information]

97. "Catalytic Enantioselective Stereoablative Alkylation of 3-Halooxindoles: Facile Access to Oxindoles with C3 All-Carbon Quaternary Stereocenters", Sandy Ma, Xiaoqing Han, Shyam Krishnan, Scott C. Virgil, and Brian M. Stoltz. Angew. Chem. Int. Ed. 200948, 8037. [Supporting Information]. (This article was also featured in Synfacts, 2010, 65. The article can be found here on the Synfacts page.)

95. "Enantioselective Protonation", Justin T. Mohr, Allen Y. Hong, and Brian M. Stoltz. (This article was featured in the Nature Chemistry first year anniversary highlights).Nature Chemistry 20091, 359.

94. "An efficient synthesis of the carbocyclic core of zoanthenol", Jennifer L. Stockdill, Douglas C. Behenna, Andrew McClory, and Brian M. Stoltz. Tetrahedron 200965, 6571. [Supporting Information]

93. "Synthetic efforts toward cyathane diterpenoid natural products", John A. Enquist Jr. and Brian M. Stoltz. Nat. Prod. Rep. 200926, 661.

92. "Unexpected decarbonylation during an acid-mediated cyclization to access the carbocyclic core of zoanthenol", Jennifer L. Stockdill, Douglas C. Behenna, and Brian M. Stoltz. Tetrahedron Lett. 200950, 3182. [Supporting Information]

91. "Preparation of (S)-2-Allyl-2-methylcyclohexanone", Justin T. Mohr, Michael R. Krout, and Brian M. Stoltz. Org. Synth. 200986, 194.

90. "Preparation of (S)-tert-ButylPHOX", Michael R. Krout, Justin T. Mohr, and Brian M. Stoltz. Org. Synth. 200986, 181.

89. "The Direct Acyl-Alkylation of Arynes. Preparation of Methyl 2-(2-AcetylPhenyl)Acetate.", David C. Ebner, Uttam K. Tambar, and Brian M. Stoltz. Org. Synth. 200986, 161.

88. "Progress toward the Synthesis of the Transtaganolide/Basiliolide Natural Products: An Ireland-Claisen Approach", Hosea M. Nelson and Brian M. Stoltz. Tetrahedron Lett. 200950, 1699.

87. "Side Chain Chemistry Mediates Backbone Fragmentation in Hydrogen Deficient Peptide Radicals", Qingyu Sun, Hosea Nelson, Tony Ly, Brian M. Stoltz and Ryan R. Julian. J. Proteome Res. 20098, 958. [Supporting Information]

86. "Enantioselective Total Synthesis of (+)-Cassiol", Krastina V. Petrova, Justin T. Mohr and Brian M. Stoltz. Org. Lett. 200911, 293. [Supporting Information]. (This article was also featured in Synfacts, 2009, 719. The article can be found here on the Synfacts page.)

85. "Catalytic Enantioselective Approach to the Eudesmane Sesquiterpenoids: Total Synthesis of (+)-Carissone", Samantha R. Levine, Michael R. Krout and Brian M. Stoltz. Org. Lett. 200911, 289. [Supporting Information]

84. "A Concise Total Synthesis of (-)-Quinocarcin via Aryne Annulation", Kevin M. Allan and Brian M. Stoltz. J. Am. Chem. Soc. 2008130, 17270. [Supporting Information]. (This article was the subject of a Chemistry World Totally Synthetic column, which can be found here.)

82. "Pd-Catalyzed Enantioselective Aerobic Oxidation of Secondary Alcohols: Applications to the Total Synthesis of Alkaloids", Shyam Krishnan, Jeffrey T. Bagdanoff, David C. Ebner, Yeeman K. Ramtohul, Uttam K. Tambar, and Brian M. Stoltz. J. Am. Chem. Soc. 2008130, 13745. [Supporting Information]

81. "Natural products as inspiration for the development of asymmetric catalysis", Justin T. Mohr, Michael R. Krout & Brian M. Stoltz. Nature 2008455, 323.

80. "Catalytic Enantioselective Alkylation of Substituted Dioxanone Enol Ethers: Ready Access to C(α)-Tetrasubstituted Hydroxyketones, Acids, and Esters", Masaki Seto, Jennifer L. Roizen, and Brian M. Stoltz. Angew. Chem. Int. Ed. 200847, 6873. [Supporting Information]. (This article was also featured in Synfacts2008, 1186. The article can be found here on the Synfacts page.)

79. "Palladium-Catalyzed Enantioselective Oxidation of Chiral Secondary Alcohols: Access to Both Enantiomeric Series", David C. Ebner, Raissa M. Trend, Cédric Genet, Matthew J. McGrath, Peter O'Brien, and Brian M. Stoltz. Angew. Chem. Int. Ed. 200847, 6367. [Supporting Information]. (This article was featured in Synfacts2009, 121. The article can be found here on the Synfacts page)

78. "The Total Synthesis of (-)-Cyanthiwigin F by means of Double Catalytic Enantioselective Alkylation", John A. Enquist Jr., Brian M. Stoltz. Nature 2008453, 1228. [Supporting Information] (This paper was the topic of a Chemistry World news article that features an interview with Brian. The article was also the subject of a Nature Chemistry research highlight. This letter was also the topic of an article in Chemical & Engineering News, as well as Synform.)

77. "The Biology and Chemistry of the Zoanthamine Alkaloids", Douglas C. Behenna, Jennifer L. Stockdill, Brian M. Stoltz. Angew. Chem. Int. Ed. 200847, 2365.

76. "Homogeneous Pd-Catalyzed Enantioselective Decarboxylative Protonation", Smaranda C. Marinescu, Toyoki Nishimata, Justin T. Mohr, and Brian M. Stoltz. Org. Lett.200810, 1039. [Supporting Information] (This publication was listed as one of the most accessed communications in Org. Lett. for the January-March 2008 period).

75. "C–H Bond Functionalizations with Palladium(II): Intramolecular Oxidative Annulations of Arenes", Eric M. Ferreira, Haiming Zhang, and Brian M. Stoltz. Tetrahedron200864, 5987.

74. "Orthogonal Synthesis of Indolines and Isoquinolines via Aryne Annulation", Christopher D. Gilmore, Kevin M. Allan, and Brian M. Stoltz. J. Am. Chem. Soc. 2008130, 1558. [Supporting Information] (This publication was listed as one of the most accessed communications in J. Am. Chem. Soc. for the January-March 2008 period).

73. "The Catalytic Asymmetric Total Synthesis of Elatol", David E. White, Ian C. Stewart, Robert H. Grubbs, and Brian M. Stoltz. J. Am. Chem. Soc. 2008130, 810. [Supporting Information]. (This article was also featured in the first issue of JACSβ. This publication was also listed as one of the most accessed communications in J. Am. Chem. Soc. for the January-March 2008 period).

71. "Enantioselective Tsuji Allylations", Justin T. Mohr and Brian M. Stoltz. Chem. Asian J. 20072, 1476. (This paper has been listed among the most accessed articles for Chem. Asian J. for the period of August 2007 through July 2008.)

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70. "Catalytic enantioselective stereoablative reactions: an unexploited approach to enantioselective catalysis", Justin T. Mohr, David C. Ebner and Brian M. Stoltz. Org. Biomol. Chem. 20075, 3571. (This paper has has been listed among the most accessed papers in Org. Biomol. Chem. for November of 2007.)

69. "Preparation of 3,3-disubstituted oxindoles by addition of malonates to 3-halo-oxindoles", Shyam Krishnan and Brian M. Stoltz. Tetrahedron Lett. 200748, 7571.

68. "The Inner-Sphere Process in the Enantioselective Tsuji Allylation Reaction with (S)-t-Bu-phosphinooxazoline Ligands", John A. Keith, Douglas C. Behenna, Justin T. Mohr, Sandy Ma, Smaranda C. Marinescu, Jonas Oxgaard, Brian M. Stoltz, and William A. Goddard, III. J. Am. Chem. Soc. 2007 129,11876. [Supporting Information]

67. "Convergency and Divergency as Strategic Elements in Total Synthesis: The Total Synthesis of (-)-Drupacine and the Formal Total Synthesis of (±)-Cephalotaxine, (-)-Cephalotaxine, and (+)-Cephalotaxine", Qi Liu, Eric M. Ferreira, and Brian M. Stoltz. J. Org. Chem. 2007 72, 7352. [Supporting Information] (This paper has been listed among the most accessed papers of J. Org. Chem. for the July-September 2007 period.)

66. "A Facile and Modular Synthesis of Phosphinooxazoline Ligands", Kousuke Tani, Douglas C. Behenna, Ryan M. McFadden, and Brian M. Stoltz. Org. Lett. 20079, 2529. [Supporting Information]

65. "Synthesis of the Carbocyclic Core of Zoanthenol: Implementation of an Unusual Acid-Catalyzed Cyclization", Douglas C. Behenna, Jennifer L. Stockdill, and Brian M. Stoltz. Angew. Chem. Int. Ed. 200746, 4077. [Supporting Information]

64. "Synthesis of 2-Quinuclidonium by Eliminating Water: Experimental Quantification of the High Basicity of Extremely Twisted Amides", Tony Ly, Michael Krout, Don K. Pham, Kousuke Tani, Brian M. Stoltz, and Ryan R. Julian. J. Am. Chem. Soc. 2007129, 1864. [Supporting Information]

63. "Oxidative Kinetic Resolution-Claisen Rearrangement Sequence to Enantioenriched Arylcycloalkenes", David C. Ebner, Zoltán Novák, and Brian M. Stoltz. Synlett200620, 3533.

62. "The development and scope of a versatile tandem Stille-oxa-electrocyclization reaction", Uttam K. Tambar, Taichi Kano, John F. Zepernick and Brian M. Stoltz. Tetrahedron Lett. 200648, 345.

61. "The synthesis of C-3β functionalized indoles via a hydroboration/Suzuki–Miyaura coupling sequence", Eric M. Ferreira and Brian M. Stoltz. Tetrahedron Lett. 2006,47, 8579.

59. "Convergent and Diastereoselective Synthesis of the Polycyclic Pyran Core of Saudin", Uttam K. Tambar, Taichi Kano, John F. Zepernick, and Brian M. Stoltz. J. Org. Chem. 200671, 8357. [Supporting Information - Experimental] [Supporting Information - Spectra]

58. "A Convergent and Enantioselective Synthesis of (+)-Amurensinine via Selective C–H and C–C Bond Insertion Reactions", Uttam K. Tambar, David C. Ebner, and Brian M. Stoltz. J. Am. Chem. Soc. 2006128, 11752. [Supporting Information]. (This publication was listed as one of the ten most accessed communications in J. Am. Chem. Soc. for the July-September 2006 period. This paper was also featured in Synfacts 2007, 2, 124.)

57. "Catalytic Enantioselective Decarboxylative Protonation", Justin T. Mohr, Toyoki Nishimata, Douglas C. Behenna, and Brian M. Stoltz. J. Am. Chem. Soc. 2006128, 11348. [Supporting Information]. (This publication has been featured on the organic-chemistry.org webportal, which can be accessed here. This paper was also featured in Synfacts 2006, 12, 1239.)

56. "A unified synthetic approach to the pyrazinone dragmacidins", Neil K. Garg and Brian M. Stoltz. Chem. Commun. 2006, 3769.

55. "Synthesis and structural analysis of 2-quinuclidonium tetrafluoroborate", Kousuke Tani and Brian M. Stoltz. Nature2006441, 731. [Supporting Information] (A forward written by Harry Wasserman was featured in the "News and Views" section of Nature, and an article about Brian was featured in the "Abstractions" section. This publication was also featured in C & E News. This synthesis of 2-quinuclidonium tetrafluoroborate was featured in an Angew. Chem. Int. Ed. article by Jonathan Clayden. Additionally, this synthesis was listed in the Chemical and Engineering News Chemistry Highlights of 2006.)

54. "The Catalytic Enantioselective, Protecting Group-Free Total Synthesis of (+)-Dichroanone", Ryan M. McFadden and Brian M. Stoltz. J. Am. Chem. Soc. 2006128, 7738. [Supporting Information]. (This synthesis was featured as a "Research Highlight" in Nature. Additionally, this synthesis was featured in an Angew. Chem. Int. Ed.review article focusing on asymmetric alkylation.)

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52. "2-Diazoacetoacetic acid, an efficient and convenient reagent for the synthesis of α-diazo-β-ketoesters", Michael E. Meyer, Eric M. Ferreira, and Brian M. Stoltz.Chem. Commun. 2006, 1316. [Supporting Information]

51. "Effects of a Modified Dye-Labeled Nucleotide Spacer Arm on Incorporation by Thermophilic DNA Polymerases", Christopher J. Lacenere, Neil K. Garg, Brian M. Stoltz, and Stephen R. Quake. Nucleosides, Nucleotides & Nucleic Acids 200625, 9.

50. "Oxidative Cyclizations in a Nonpolar Solvent Using Molecular Oxygen and Studies on the Stereochemistry of Oxypalladation", Raissa M. Trend, Yeeman K. Ramtohul, and Brian M. Stoltz. J. Am. Chem. Soc. 2005127, 17778. [Supporting Information] (This article was listed as a 'Hot Paper' for National Chemistry Week 2006.)

49. "Deracemization of Quaternary Stereocenters by Pd-Catalyzed Enantioconvergent Decarboxylative Allylation of Racemic β-Ketoesters", Justin T. Mohr, Douglas C. Behenna, Andrew M. Harned and Brian M. Stoltz. Angew. Chem. Int. Ed. 200544, 6924. [Supporting Information] (This paper was featured on organic-chemistry.org, as well as an Angew. Chem. Int. Ed. review article focusing on asymmetric alkylation. This paper was also featured in Synfacts 2006, 1, 53.)

48. "A Ligand-Free Solid-Supported System for Sonogashira Couplings: Applications in Nucleoside Chemistry", Neil K. Garg, Carolyn C. Woodroofe, Christopher J. Lacenere, Stephen R. Quake and Brian M. Stoltz. Chem. Commun. 2005, 4551. [Supporting Information]

47. "Heterogeneous Reductive Isomerization Reaction Using Catalytic Pd/C and H2", Daniel D. Caspi, Neil K. Garg, and Brian M. Stoltz. Org. Lett. 20057, 2513. [Supporting Information]

45. "Development of an Enantiodivergent Strategy for the Total Synthesis of (+)- and (–)-Dragmacidin F from a Single Enantiomer of Quinic Acid", Neil K. Garg, Daniel D. Caspi, and Brian M. Stoltz. J. Am. Chem. Soc. 2005127, 5970. [Supporting Information] (This paper was featured in Synfacts 2005, 2, 184.)

42. "Synthesis of bis(indole)-1,2,4-triazinones", Neil K. Garg and Brian M. Stoltz. Tetrahedron Lett. 200546, 1997.

40. "The Enantioselective Tsuji Allylation", Douglas C. Behenna and Brian M. Stoltz. J. Am. Chem. Soc. 2004126, 15044. [Supporting Information]. (This paper was featured in an Angew. Chem. Int. Ed. review article focusing on asymmetric alkylation.)

39. "The Total Synthesis of (+)-Dragmacidin F", Neil K. Garg, Daniel D. Caspi, and Brian M. Stoltz. J. Am. Chem. Soc. 2004126, 9552. [Supporting Information]

38. "A Computational Model Relating Structure and Reactivity in Enantioselective Oxidations of Secondary Alcohols by (-)-Sparteine-PdII Complexes", Robert J. Nielsen, Jason M. Keith, Brian M. Stoltz, and William A. Goddard, III. J. Am. Chem. Soc. 2004126, 7967. [Supporting Information]

34. "Palladium-Catalyzed Oxidative Kinetic Resolution with Ambient Air as the Stoichiometric Oxidation Gas", Jeffrey T. Bagdanoff and Brian M. Stoltz. Angew. Chem. Int. Ed. 200443, 353. [Supporting Information]

33. "Substituent Effects and Nearly Degenerate Transition States: Rational Design of Substrates for the Tandem Wolff-Cope Reaction", Julius T. Su, Richmond Sarpong, Brian M. Stoltz, and William A. Goddard III. J. Am. Chem. Soc. 2004126, 24. [Supporting Information]

32. "The Total Synthesis of (-)-Lemonomycin", Eric R. Ashley, Ernest G. Cruz, and Brian M. Stoltz. J. Am. Chem. Soc. 2003125, 15000. [Supporting Information]

31. "The Development of a Facile Tandem Wolff/Cope Rearrangement for the Synthesis of Fused Carbocyclic Skeletons", Richmond Sarpong, Julius T. Su, and Brian M. Stoltz. J. Am. Chem. Soc. 2003125, 13624. [Supporting Information]

28. "Biomimetic Approaches to Gas Phase Peptide Chemistry: Combining Selective Binding Motifs with Reactive Carbene Precursors to Form Molecular Mousetraps", Ryan R. Julian, Jeremy A. May, Brian M. Stoltz, and J. L. Beauchamp. Int. J. Mass Spectrom. 2003228(2-3), 851-64.

27. "Gas Phase Synthesis of Charged Copper and Silver Fischer Carbenes from Diazomalonates: Mechanistic and Conformational Considerations in Metal Mediated Wolff Rearrangements", Ryan R. Julian, Jeremy A. May, Brian M. Stoltz, and J. L. Beauchamp. J. Am. Chem. Soc. 2003125, 4478.

24. "Biomimetic approach to communesin B (a.k.a. nomofungin)", Jeremy A. May, Ryan K. Zeidan, and Brian M. Stoltz. Tetrahedron Lett. 200344, 1203.

23. "The First Total Synthesis of Dragmacidin D", Neil K. Garg, Richmond Sarpong, and Brian M. Stoltz. J. Am. Chem. Soc. 2002124, 13179. [Supporting Information]

21. "Molecular recognition of arginine in small peptides by supramolecular complexation with dibenzo-30-crown-10 ether", Ryan R. Julian, Minta Akin, Jeremy A. May, Brian M. Stoltz, and J. L. Beauchamp. Int. J. Mass Spectrom. 2002220, 87.

20. "Progress Toward the Synthesis of Garsubellin A and Related Phloroglucins: The Direct Diastereoselective Synthesis of the Bicyclo[3.3.1]nonane Core", Sarah J. Spessard and Brian M. Stoltz. Org. Lett. 20024, 1943. [Supporting Information]

Brian's Graduate and Postdoctoral Publications


18. "Welwitindolinone C synthetic studies. Construction of the welwitindolinone carbon skeleton via a transannular nitrone cycloaddition", David B. Freeman, Alexandra A. Holubec, Matthew W. Weiss, Julie A. Dixon, Akio Kakefuda, Masami Ohtsuka, Munenori Inoue, Rishi G. Vaswani, Hidenori Ohki, Brian D. Doan, Sarah E. Reisman, Brian M. Stoltz, Joshua J. Day, Ran N. Tao, Noah A. Dieterich, John L. Wood. Tetrahedron 2010Article In Press.

17. "Synthesis of C(3) Benzofuran-Derived Bisaryl Quaternary Centers: Approaches to Diazonamide A", Douglas E. Fuerst, Brian M. Stoltz, and John L. Wood. Org. Lett.20002, 3521. [Supporting Information]

16. "Enantioselective Total Synthesis of Nicandrenones", Brian M. Stoltz, Taichi Kano, and E. J. Corey. J. Am. Chem. Soc. 2000122, 9044. [Supporting Information]

15. "Mechanistic Insights into the Factors Determining Exo-Endo Selectivity in the Lewis Acid-Catalyzed Diels-Alder Reaction of 1,3-Dienes with 2-Cycloalkenones", Min Ge, Brian M. Stoltz, and E. J. Corey. Org. Lett. 20002, 1927.

14. "Cuprous Chloride Accelerated Stille Reactions. A General and Effective Coupling System for Sterically Congested Substrates and for Enantioselective Synthesis", Xiaojun Han, Brian M. Stoltz, and E. J. Corey. J. Am. Chem. Soc. 1999121, 7600. [Supporting Information]

13. "A Simple and Effective Procedure for Removal of Tri-n-butyltin Halides from Reaction Mixtures", Benjamin S. Edelson, Brian M. Stoltz and E. J. Corey. Tetrahedron Lett. 199940, 6729.

12. "Novel Annulation Products Derived by Selective Attack on the C(18) Angular Methyl Group of the Cardenolide Ouabain", E. J. Corey and Brian M. Stoltz. Tetrahedron Lett. 199940, 2061.

11. "Total Synthesis and Protein Kinase Activity of C(7) Methyl Derivatives of K252a", John L. Wood, Dejah T. Petsch, Brian M. Stoltz, Elizabeth M. Hawkins, Daniel Elbaum, and David R. Stover. Synthesis 1999Sup. 1, 1529.

10. "Application of Reactive Enols in Synthesis: A Versatile Efficient and Stereoselective Construction of the Welwitindolinone Carbon Skeleton", John L. Wood, Alexandra A. Holubec, Brian M. Stoltz, Matthew M. Weiss, Julie A. Dixon, Brian D. Doan, Mohammed F. Shamji, Jennifer M. Chen, and Timothy P. Heffron. J. Am. Chem. Soc. 1999121, 6326. [Supporting Information]

9. "Development of a Rhodium Carbenoid-Initiated Claisen Rearrangement for the Enantioselective Synthesis of α-Hydroxy Carbonyl Compounds", John L. Wood, George A. Moniz, Derek A. Pflum, Brian M. Stoltz, Alexandra A. Holubec, and Hans-Jürgen Dietrich. J. Am. Chem. Soc. 1999121, 1748. [Supporting Information]

8. "The Design and Implementation of an Efficient Synthetic Approach to Pyranosylated Indolocarbazoles: The Total Synthesis of (+)-RK286c, (+)-MLR-52, (+)-Staurosporine, and (-)-TAN-1030a", John L. Wood, Brian M. Stoltz, Steven N. Goodman, and Kenolisa Onwueme. J. Am. Chem. Soc. 1997119, 9652. [Supporting Information]

7. "The Design and Implementation of an Efficient Synthetic Approach to Furanosylated Indolocarbazoles: The Total Synthesis of (+)- and (-)-K252a", John L. Wood, Brian M. Stoltz, Hans-Jürgen Dietrich, Derek A. Pflum, and Dejah T. Petsch. J. Am. Chem. Soc. 1997119, 9641. [Supporting Information]

6. "The Total Synthesis of Indolocarbazole Natural Products K252c, (+)-K252a, (+)-RK-286c, (+)-MLR-52, (-)-TAN-1030a, and (+)-Staurosporine", Brian M. Stoltz, Ph.D. Thesis, Yale UniversityMay 1997.

5. "The Total Synthesis of (+)-RK-286c, (+)-MLR-52, (+)-Staurosporine and (+)-K252a", John L. Wood, Brian M. Stoltz, and Steven N. Goodman. J. Am. Chem. Soc.1996118, 10656. [Supporting Information]. (This paper was featured in a C&EN. News of the Week article.)

4. "The Synthesis of Desamido Analogs of Staurosporine, RK-286c, and TAN-1030a. A Model for the Synthesis of Both Furanosylated and Pyranosylated Indolocarbazole Natural Products", John L. Wood, Brian M. Stoltz, Kenolisa Onwueme and Steven N. Goodman. Tetrahedron Lett. 199637, 7335.

3. "The Stereoselective Ring Contraction of a Pyranosylated Indolocarbazole. A Biosynthetic Link Between K252a and Staurosporine?", Brian M. Stoltz and John L. Wood. Tetrahedron Lett. 199637, 3929.

2. "A Ring Expansion Approach to Pyranosylated Indolocarbazoles", Brian M. Stoltz and John L. Wood. Tetrahedron Lett. 199536, 8543.

1. "The Total Synthesis of (+)- and (-)-K252a", John L. Wood, Brian M. Stoltz, and Hans-Jürgen Dietrich. J. Am. Chem. Soc. 1995117, 10413.

Patents


"Palladium-catalyzed decarbonylation of fatty acid anhydrides for the production of linear alpha olefins", Yiyang Liu, Brian M. Stoltz, Robert H. Grubbs, Alexey Fedorov, and Kelly E. Kim United States Patent US 9440891, 2016.

"Synthetic Transtaganolide and Basiliolide Products, and Synthesis Methods Thereof", Hosea Nelson, Kei Murakami, Scott C. Virgil, Brian M. Stoltz, Jonathan R. Gordon.United States Patent US 9422259, 2016.

"Method of preparing Z-alkene-containing insect pheromones", Eric A. Bercot and Brian M. Stoltz. United States Patent US 9181164, 2015.

"Inhibitors of P97", Steven J. Brown, Tsui-Fen Chou, Raymond Deshaies, Amanda C. Jones, Hugh Rosen, Brian M. Stoltz. United States Patent US 9089572, 2015.

"Synthetic Transtaganolide and Basiliolide Products, and Synthesis Methods Thereof", Hosea Nelson, Kei Murakami, Scott C. Virgil, Brian M. Stoltz, Jonathan R. Gordon.United States Patent US 8912347, 2014.

"Quaternary Heteroatom Containing Compounds,", Brian M. Stoltz, Scott C. Virgil, David E. White, Taiga Yurino, Yiyang Liu, Douglas C. Behenna, Douglas Duquette, and Christian Eidamshaus. United States Patent US 8822679, 2014.

"Liphagal Enantiomers and their Derivatives and Precursors, and Enantioselective Methods of Making the Same,", Brian M. Stoltz, Ryan McFadden, Scott C. Virgil, Helene Kolding, Jennifer L. Alleva, and Joshua J. Day United States Patent US 8653307, 2014.

"Certain Chemical Entities, Compositions, and Methods", Zhe Yang, Scott Collibee, Alex R. Muci, Jianchao Wang, Luke W. Ashcraft, Jeff Gardina, Brian M. Stoltz, Gustave Bergnes, and Bradley P. Morgan. United States Patent US 7989469, 2011.

"Enantioselective, Catalytic Allylation of Ketones and Olefins", Douglas C. Behenna, Brian M. Stoltz, Justin T. Mohr, Andrew M. Harned. United States Patent US 7235698,2007.

"Methods and Compositions for Enantioselective Oxidation Reactions", Eric M. Ferreira, Brian M. Stoltz. United States Patent US 7166754, 2007.

"Chemical Reagents Capable of Selective Attachment to and Reaction with Peptides and Proteins", Jesse L. Beauchamp, Ryan R. Julian, Brian M. Stoltz and Jeremy A. May.United States Patent Application US 2005/0010059, 2005.

"Glycosylated Indolocarbazole Synthesis", John L. Wood, Brian M. Stoltz, Hans-Jürgen Dietrich, and Derek A. Pflum. Worldwide Patent WO 9707081, 1997. Also United States Patent US 7038043 and United States Patent US 6037468.